Quantitative Texture Analysis with the HIPPO TOF Diffractometer

One of the design goals of the neutron time-of-flight (TOF) diffractometer HIPPO (HIgh Pressure Preferred Orientation) at LANSCE (Los Alamos Neutron Science Center) was efficient quantitative texture analysis. In this paper, the effects of the HIPPO detector geometry and layout on texture analysis, particularly the shape and dimensions of the detector panels, are investigated in detail. An equal-channel angular-pressed (ECAP) aluminum-sample with a strong texture was used to determine the methodological limitations of various methods of quantitative texture analysis. Several algorithms for extracting the orientation distribution function (ODF) from the TOF-spectra are compared: discrete orientations at arbitrary positions, harmonic method in Rietveld codes (MAUD and GSAS) and discrete methods in MAUD. Because of the detector geometry, the sharpest texture peaks that can be represented are 12-15° in width, resulting in an optimal texture resolution of 25-30°. Due to the limited resolution and incomplete pole figure coverage, harmonic expansions beyond L = 12 introduce subsidiary oscillations, which are consistently identified as artifacts. Only discrete methods provide a quantitative representation of the texture. Harmonic methods are adequate for a qualitative description if the main texture component. The results of our analysis establish HIPPO as an efficient instrument to determine preferred orientations in relatively short measuring times.